1. Properties
The properties of platinum-rhodium alloy change regularly with the increase of Rhodium content:
(1) lattice constant and density decrease smoothly. (2) Increased mechanical properties. Due to
the stability of component properties and structure, platinum-rhodium alloys have very stable
mechanical properties at high temperature, especially those with rhodium content less than
25%. (3) With the increase of resistivity, the resistance temperature coefficient decreases.
(4) The thermoelectric potential and its stability increase, but the stability decreases when the
alloy is polluted. (5) Rhodium can reduce the volatilization loss of platinum in the alloy when
heated in high temperature oxidation atmosphere. (6) Enhanced acid corrosion resistance,
alloy containing more than 20% rhodium is insoluble in aqua regia. (7) platinum-rhodium alloy
has high catalytic activity. (8) platinum-rhodium alloy is generally easy to process, but the high
Rhodium alloy has low plasticity, so it has to be cogging down by hot working.
2. Application
High melting point, excellent chemical, mechanical and thermoelectric stability as well as high
catalytic activity, determine that platinum-rhodium alloys are more widespread and important
than any other noble metal alloys for industrial applications. Mainly used for: (1) thermocouple
manufacturing. PtRh10/Pt thermocouple is the most accurate temperature measurement above
300℃, is also 630.74 ~ 1064.43℃ in the temperature area of the international temperature benchmark,
generally measured temperature up to 1350℃(short time up to 1600℃); PtRh30/PtRh6,
PtRh13/Pt, PtRh20/PtRh5, PtRh40/PtRh20 and other thermocouples can measure higher
temperatures. (2) in the glass industry, it is used to make crucible, leakage plate, agitator,
electrode and other heat resistant and corrosion resistant devices. (3) as a catalyst in
ammonia oxidation and many other reactions. (4) as a high temperature heating body,
in which the furnace with PtRh40 alloy as heating body can work in the oxidation
atmosphere to 1800℃. (5) In the instrument industry used as electrical contacts, spark plug
electrode and potentiometer winding material. Typical platinum-rhodium alloys are PtRh3.5,
PtRh7, PtRh10, PtRh25 and PtRh40, of which PtRh10 is known as the "standard alloy" and
is the most widely used.
3. Properties of PtRh30
Density: 17.61 g/cm3
Tensile Strength: >480 Mpa
Resistivity at 20℃:19.00 μ Ω·cm
Vickers Hardness: > 250 HV
Melting Point: 1927 ℃
4. Chemical Composition: ( % )
Pt 70±0.5 Rh 30±0.5 Pd<0.0005 Ir<0.0005 Ag<0.0003 Au<0.0005
Fe<0.0005 Ni<0.0005 Al<0.0003 Pb<0.0008 Mg<0.0002 Si<0.001
Ti<0.0003 Cr<0.0003 Cu<0.0003 Mn<0.0002